Journal
DESALINATION
Volume 500, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.desal.2020.114897
Keywords
Capacitive deionization; V2O5; MXenes; Nanocuboid; Desalination
Categories
Funding
- National Natural Science Foundation of China [21777118]
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"The study demonstrates that the one-dimensional V2O5 with nanocuboid structure prepared from MXenes(V2C) precursor shows high adsorption capacity and fast ion diffusion ability, achieving a salt adsorption capacity of 55.2 mg NaCl g(-1) V2O5. The high conductivity and low charge transfer resistance of V2O5 electrode lead to reduced energy loss during desalination, resulting in a low energy consumption of 0.27 kWh kg(1)-NaCl. V2O5 is considered as a promising electrode material for practical CDI application in the future."
Capacitive desalination (CDI) has aroused much attention due to its advantages of low energy consumption and environmental compatibility. However, typical CDI processes display limited efficiency. In this work, onedimensional V2O5 with nanocuboid structure was prepared with MXenes(V2C) precursor for the first time, which has high adsorption capacity, structure stability and fast ion diffusion ability. The as-synthesized V2O5 electrode achieved a salt adsorption capacity(SAC) of 55.2 mg NaCl g(-1) V2O5 under optimized conditions with a constant current density of 30 mA g(-1), a voltage range from -0.6 to 1.2 V, and an initial solution of 500 mg L-1 NaCl. Furthermore, from the comprehensive analysis of mechanism, due to the high conductivity and low charge transfer resistance of V2O5 electrode, it reduces the energy loss of the resistance during desalination. A particularly low energy consumption of 0.27 kWh kg(1)-NaCl is reached when the operation is carried out successfully at low voltage range, indicating the advantages of energy saving and high efficiency. Therefore, V2O5 is an attractive and promising electrode material, which exhibits the potential of pseudocapacitive materials with certain structure for practical CDI application in future and inspires us to have a deep insight into the effect of morphology on the properties.
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