Material characterization of a pultrusion specific and highly reactive polyurethane resin system: Elastic modulus, rheology, and reaction kinetics

This study presents a detailed material characterization study of a pultrusion specific polyurethane resin system. Firstly, the chemical behaviour was characterized by utilizing differential scanning calorimetry. The cure kinetics was fitted well to an autocatalytic cure kinetics model with Arrhenius temperature dependency. The resin system did not show any inhibition time. Then, the viscosity evolution was observed using a rheometer. From these measurements, the gelation point was estimated from the criterion of cross-over point of storage and loss modulus curves. The corresponding cure degree of gelation point was found to be 0.79 using the cure kinetics model. The complex viscosity evolution through dynamic scans was predicted well with a cure degree and temperature dependent viscosity model. The elastic modulus and glass transition temperature of fully and partially cured samples were measured by means of DMA in tension mode. A five step cure hardening instantaneous linear elastic model was fitted well to a wide range of cure degree values after gelation. Lastly, the fitted material models were employed in a case study of a typical pultrusion process to visualize the effects of pulling speed on the material property evolution.

Automated summary

This study characterized the chemical behavior, cure kinetics, and viscosity evolution of a polyurethane resin system for pultrusion. The gelation point was estimated from the cross-over point of storage and loss modulus curves, and the corresponding cure degree was determined using a cure kinetics model. DMA was used to measure the elastic modulus and glass transition temperature of fully and partially cured samples. A five-step cure hardening model was well fitted to a wide range of cure degree values after gelation. These material models were then applied to a case study of a typical pultrusion process to study the effects of pulling speed on material property evolution.