4.7 Article

Synthesis of MOF-derived Fe7S8/C rod-like composites by controlled proportion of carbon for highly efficient electromagnetic wave absorption

Journal

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.compositesa.2020.106246

Keywords

Electromagnetic wave absorption; Carbon proportion; Impedance matching; Synergistic effect

Funding

  1. National Natural Science Foundation of China [51572157, 21902085, 51702188]
  2. Fundamental Research Funds for the Central Universities [2018JC046, 2018JC036]
  3. Young Scholars Program of Shandong University [2018WLJH25]

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By controlling the dosage of ferric salt added, the proportion of Fe7S8 and carbon in composites can be adjusted to achieve synergistic effect and improve the electromagnetic wave absorption performance.
In this study, we firstly used the MOF-derived Fe7S8/C rod-like composites as absorbers and systematically investigated the synergistic effect of Fe7S8 and carbon in electromagnetic wave absorption applications. By controlling the introduced dosage of ferric salt, the proportion of carbon and Fe7S8 in composites could be adjusted, which made a significant effect on the electromagnetic parameters and absorption performance. When the carbon proportion was about 33.9 wt%, the synergistic effect between Fe7S8 and carbon guaranteed the optimized impedance matching and strong dissipation ability, presenting superb absorption performance. The optimal performance reflected in the minimum reflection loss of -68.86 dB at 12.08 GHz with a thickness of 1.67 mm, and the effective bandwidth was up to 4.56 GHz at 1.45 mm. Therefore, this study provides a facile method for preparing the Fe7S8/C absorbers and emphasizes the significance of the ratios between Fe7S8 and carbon on the electromagnetic parameters and absorption performance.

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