4.4 Review

Recent Progress and Perspectives of Sodium Metal Anodes for Rechargeable Batteries

Journal

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
Volume 37, Issue 2, Pages 189-199

Publisher

HIGHER EDUCATION PRESS
DOI: 10.1007/s40242-021-0449-3

Keywords

Solid electrolyte interphase; Dendrite growth; Sodium protection; Sodium metal anode

Funding

  1. National Natural Science Foundation of China [51761165025, 21822506, 52001700]
  2. Natural Science Foundation of Tianjin City, China [19JCJQJC62400]
  3. 111 Project of China

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This review summarizes the recent progress on Na anode protection in sodium metal batteries, including strategies such as modified three-dimensional current collectors, artificial solid electrolyte interphases, and electrolyte modifications. Conclusions and perspectives are provided for further understanding and development of Na metal anodes.
Sodium metal anodes have attracted significant attention due to their high specific capacity, low redox potential and abundant resources. However, the dendrites and unstable solid electrolyte interphase(SEI) of sodium anodes restrict the development of sodium metal batteries. This review includes the recent progress on the Na anode protection in sodium metal batteries. The strategies are summarized as modified three-dimensional current collectors, artificial solid electrolyte interphases, and electrolyte modifications. Conclusions and perspectives are envisaged for the further understanding and development of Na metal anodes.

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