Microwave dielectric characterization of Ca0.6(La1-xYx)0.2667TiO3 perovskite ceramics with high positive temperature coefficient

Solid solution Ca0.6(La1-xYx)0.2667TiO3 dielectric ceramic systems with various x values were studied, which were prepared using a solid-state reaction method. X-ray diffraction and X-ray spectroscopy analyses showed that the crystal structure of these samples was orthorhombic perovskite. The microstructures with the substitution amount of Y3+ and the dielectric performances of the Ca0.6(La1-xYx)0.2667TiO3 ceramics were also explored. With x = 0.1, the Ca0.6(La0.9Y0.1)0.2667TiO3 ceramic could be sintered at 1350 C, and the microwave dielectric performance was found to be strongly correlated with the sintering temperature. A maximum Qf value of 23,100 (GHz), dielectric constant (epsilon r) of 111, and temperature coefficient (tau f) of 374.6 ppm/C were achieved for samples sintered at 1350 C for 4 h. This dielectric ceramic possessed good potential as a tau f compensator to obtain a near-zero tau f mixture for high-quality substrates for use in wireless communication systems.

Automated summary

Solid solution Ca0.6(La1-xYx)0.2667TiO3 dielectric ceramic systems were studied with various x values, showing an orthorhombic perovskite crystal structure. The Ca0.6(La0.9Y0.1)0.2667TiO3 ceramic sintered at 1350 C for 4 h exhibited excellent microwave dielectric performance with a maximum Qf value of 23,100 (GHz), dielectric constant (εr) of 111, and temperature coefficient (τf) of 374.6 ppm/C, making it a promising material for wireless communication systems.