4.7 Article

Effect of substrate morphology on the deposition behavior of α-Al2O3 films by room temperature granule spray in vacuum process

Journal

CERAMICS INTERNATIONAL
Volume 47, Issue 12, Pages 16708-16715

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2021.02.241

Keywords

Al2O3 film; GSV; Surface morphology; Deposition behavior

Funding

  1. National Research Foundation of Korea [NRF2019R1A2B5B01070100]

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The surface morphology of a hard substrate significantly influences the deposition behavior, adhesion strength, and residual surface stress of alpha-Al2O3 films. Different surface morphologies of the hard substrate result in variations in the deposition characteristics.
In this study, we investigated the influence of surface morphology of a hard substrate on the deposition behavior of alpha-Al2O3 films coated by a granule spray in vacuum (GSV) process at room temperature. Three types of alpha-Al2O3 films were prepared by chemical vapor deposition (CVD) on a WC-Co base material: (006) textured film with a uniform and small mold-type morphology, (110) and (012) textured films with large grains and a relatively flat morphology, and flat (006) textured film after polishing. These CVD alpha-Al2O3 films were further coated with nanograined alpha-Al2O3 films by the GSV process. The deposition behavior, adhesion strength, and residual surface stress were found to be strongly influenced by the surface morphology of the hard substrate. For the (006) textured CVD alpha-Al2O3 film with steep crests and troughs on the surface, the GSV alpha-Al2O3 film was deposited uniformly, possibly because the powder can be directly anchored by the molding effect and subsequent hammering effect. Such different deposition characteristics also led to a variation in the surface residual stress.

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