4.7 Article

A facile platform for the synthesis of metal-oxide composites

Journal

CERAMICS INTERNATIONAL
Volume 47, Issue 5, Pages 6972-6981

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2020.11.046

Keywords

Milling; Electron microscopy; La0.25Ce0.52Nd0.17Pr0.06 alloy; Chemical properties

Funding

  1. Universidad Nacional del Comahue [PI B202-2017-2020]

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This study presents a versatile platform for the production of metal-oxide composites, demonstrating the synthesis of a La0.25Ce0.52Nd0.17Pr0.06O2 - 3Ni composite through a two-step method. The tunable microstructure of the composite allows for various technological applications.
A versatile platform for the production of metal-oxide composites is reported in this work. A La0.25Ce0.52Nd0.17Pr0.06O2 - 3Ni composite is selected for this study. The composite is fabricated in a two-step method including mechanical milling of the metals/alloys and thermal treatment in air and H-2. The mechanism of synthesis includes the structural transformation from cubic to hexagonal of the polymorphs present in the starting La0.25Ce0.52Nd0.17Pr0.06 alloy. The transformation is induced by milling. As a part of the analysis, the enthalpy of formation of the La0.25Ce0.52Nd0.17Pr0.06O2 compound is reported. The work reports a platform for the synthesis of composites. The microstructure of the composites is tunable for the use in different technological applications.

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