4.7 Article

Lead-free low-melting-point glass as bonding agent for TiO2 nanoparticles

Journal

CERAMICS INTERNATIONAL
Volume 47, Issue 5, Pages 6114-6120

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2020.10.190

Keywords

Nanoparticles; Photocatalysis; TiO2; Glass

Funding

  1. CSIC [201960E103]
  2. Spanish Ministry of Science Innovation and Universities (MCIU/AEI/FEDER, UE) [RTI2018-094958-B-I00]
  3. Spanish Ministry of Economy and Competitiveness [RYC-2016-20915]

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This study investigates the properties of TiO2-anatase nanoparticles attached by a low-melting point inorganic glass. The composition does not contain toxic metals and shows excellent wettability on ceramic nanoparticles. The mechanical strength of the composites is remarkably enhanced by adding a small amount of glass, and the self-cleaning properties of TiO2-anatase are not affected by the presence of the glass.
This work is a study of the properties of TiO2-anatase nanoparticles attached by a low-melting point inorganic glass (530 degrees C). Unlike other low-melting glasses, this composition does not contain any toxic metal. Likewise, it shows an excellent wettability on ceramic nanoparticles. A small addition of 5 vol% of glass remarkably enhances the mechanical strength of the composites with respect to pure TiO2 calcined at the same temperature, becoming twice this value. Self-cleaning properties analyzed using the methylene blue 385 nm UV-A photodegradation test showed that, after different UV-light periods, the photo-efficiency of TiO2-anatase was not altered by the presence of this glass.

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