Journal
CATALYSIS LETTERS
Volume 151, Issue 12, Pages 3509-3515Publisher
SPRINGER
DOI: 10.1007/s10562-021-03578-9
Keywords
Hydrosilylation; Aldehydes; Ketones; Solvent-free; Iron; PBP ligand
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Funding
- National Natural Science Foundation of China [21571052, U1804253, 21771057]
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An efficient solvent-free catalyst system for hydrosilylation of aldehydes and ketones, based on iron pre-catalyst Fe-2(CO)(9)/C6H4-o-(NCH2PPh2)(2)BH, showed good tolerance towards many functional groups, with corresponding alcohols obtained in high yields following basic hydrolysis of the reaction products. The reaction is likely catalyzed by an in situ generated pincer ligated iron hydride complex.
An efficient solvent-free catalyst system for hydrosilylation of aldehydes and ketones was developed based on iron pre-catalyst Fe-2(CO)(9)/C6H4-o-(NCH2PPh2)(2)BH. The reactions were tolerant of many functional groups and the corresponding alcohols were isolated in good to excellent yields following basic hydrolysis of the reaction products. The reaction is likely catalyzed by an in situ generated pincer ligated iron hydride complex. Graphic
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