High crystallinity of tunicate cellulose nanofibers for high-performance engineering films

Tunicate cellulose nanofibers (CNFs) have received widespread attention as renewable and eco-friendly engineering materials because of their high crystallinity and mechanical stiffness. Here, we report the effects of disintegration process conditions on structure-property relationships of tunicate CNFs. By varying the hydrolysis time, we could establish a correlation between crystallinity of the CNFs with linearity and stiffness, which produces different molecular ordering within their nanostructured films. Despite having identical raw materials, tensile strength and thermal conductivity of the resulting layered films varied widely, ranging from 95.6 to 205 MPa and from 1.08 to 2.37 W/mK respectively. Furthermore, nanolayered CNF films provided highly anisotropic thermal conductivities with an in- and through-plane ratio of 21.5. Our systematic investigations will provide general and practical strategies in tailoring material properties for emerging engineering applications, including flexible paper electronics, heat sink adhesives and biodegradable, implantable devices.

Automated summary

The study investigates the effect of disintegration process conditions on the structure and properties of tunicate cellulose nanofibers, revealing different mechanical and thermal conductive properties in the resulting nanostructured films under varying hydrolysis times. Nanolayered CNF films show highly anisotropic thermal conductivities, offering practical material strategies for emerging engineering applications.