Synergistic preparation of modified alginate aerogel with melamine/chitosan for efficiently selective adsorption of lead ions

Superior mechanical properties, high adsorption capacity, and excellent regeneration property are crucial design criterions to develop a new-type aerogel for adsorptive applications towards heavy metal removal from water. Herein, chitosan and melamine not only introduced abundant functional groups to increase adsorbing sites for lead ions, but also reinforced the three-dimensional network skeleton structure of absorbents to improve the service life in adsorption applications. As-fabricated alginate/melamine/chitosan aerogel can extract Pb (II) from aqueous solution efficiently, i.e., the optimum adsorption quantity of 1331.6 mg/g at pH 5.5, which exhibited excellent and selective adsorption capacity for Pb (II) against the competition of coexisting divalent metal ions. More importantly, alginate/melamine/chitosan aerogel could be regenerated using dilute acidic solution and recovered well after eight adsorption-desorption cycles. This work might offer a new idea for design and preparation of biomass-based aerogel sorbents with promising prospect in the remediation of Pb (II)-contaminated wastewater.

Automated summary

A new aerogel with superior mechanical properties, high adsorption capacity, and excellent regeneration property has been developed for heavy metal removal from water. The alginate/melamine/chitosan aerogel efficiently extracts Pb(II) from aqueous solution, showing excellent and selective adsorption capacity, and can be regenerated using dilute acidic solution.