Journal
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
Volume 94, Issue 2, Pages 513-524Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.20200321
Keywords
Alkylsilyl peroxides; Alkyl radicals; ss-Scission
Categories
Funding
- JSPS KAKENHI [JP26220803, JP17H06450]
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This account discusses the development of efficient methods for generating alkyl radicals from organosilicon peroxides and their applications in selective alkylation reactions, providing a new pathway for the formation of various carbon-carbon and carbon-heteroatom bonds under mild conditions.
This account highlights the development of efficient methods for generation of alkyl radicals from organosilicon peroxides and their applications in selective alkylation reactions. Compared with commonly used organic peroxides, a more diverse range of organosilicon peroxides can be prepared as bench-stable alkyl radical precursors, and their use in combination with transition metal catalysts allows for generation of alkyl radicals under mild conditions. Consequently, these methods have opened up a new way for the formation of various carbon-carbon and carbon-heteroatom bonds, affording highly functionalized carbon skeletons in chemoselective or asymmetric manners.
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