4.7 Article

Gas sensing behavior of ZnO toward H2 at temperatures below 300°C and its dependence on humidity and Pt-decoration

Journal

APPLIED SURFACE SCIENCE
Volume 541, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.apsusc.2020.148551

Keywords

ZnO; Hydrogen; Metal oxide semiconductor (MOS) gas sensor; Humidity; Pt decoration

Funding

  1. Ministry of Science and Technology (MOST), Taiwan, ROC [MOST105-2221-E-009-052-MY3]

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The sensing reaction mechanism of ZnO towards H-2 was investigated, showing distinct response features at temperatures above 150 degrees C. Humidity affects sensor performance, while Pt decoration greatly improves sensor performance in both dry and humid environments. This improvement is attributed to hydrogen spillover from Pt nanoparticles to the ZnO support.
The sensing reaction mechanism of ZnO toward H-2 was studied, and the effect of humidity and Pt decoration on the sensor performance was also investigated. Sputter-deposited ZnO thin films exhibit a distinct sensing response to H-2 at temperatures above 150 degrees C. An inverse V-shape response feature may develop upon the H-2 exposure depending on the H-2 concentration and the working temperature. The characteristic response feature results from a series of surface processes occurring on the ZnO surface, including ZnO reduction, Zn nanocluster growth, O-2 adsorption on Zn nanoclusters and reoxidation of the nanoclusters. The sensor response to H-2 is greatly deteriorated in humid ambient. However, the sensor shows a response enhancement toward humid H-2 gas mixtures if the sensor surface is prepared to be initially free from H2O adspecies. This suggests that coexistence of hydrogen and water adspecies on the ZnO surface improves the sensor response to H-2. When the ZnO thin film is decorated with Pt nanoparticles, the sensor performance is greatly improved both in dry and in humid environments. The improvement is proposed to result from hydrogen spillover from Pt nanoparticles to the ZnO support, which enhances the reaction rate of ZnO reduction by hydrogen adatoms.

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