Journal
APPLIED CATALYSIS B-ENVIRONMENTAL
Volume 282, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.apcatb.2020.119580
Keywords
TiO2; Photocatalysis Oxygen vacancy; N-2 fixation; Hydrophobized
Funding
- National Natural Science Foundation of China [21801092, 21872022, 21573039, 21978110, 51772126, 21671011, 21872001]
- program for the development of Science and technology of Jilin province [20180520002JH]
- Graduate Innovation Project of Jilin Normal University [201941]
- Jilin Province Science and Technology Department Program [20200801040GH]
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The research utilizes a photocatalyst with surface oxygen vacancies and F modified surface to enhance N-2 adsorption and activation, achieving higher efficiency in generating ammonia.
Photocatalytic N-2 fixation (PNF) provides a low-cost route to generate ammonia. The poor conversion efficiency from photon to ammonia seriously hinders the step forward because of the low concentration of N-2 molecules. Herein, we demonstrate a photocatalyst with surface oxygen vacancies (Vo) and a F modified surface to facilitate N-2 adsorption and activation on the surface of catalysts. The Vo site promotes the chemical adsorption of N-2, electron transfer from catalyst to N-2. F modification switches the TiO2 surface properties from hydrophilic to aerophilic, thus facilitating the adsorption of N-2. Meanwhile, the hydrogen reduction reaction (HER) is sup-pressed, as protons hard to adsorb on F capped surfaces. The optimal NH3 production rate can reach 206 mu molh(-1)g(-1), which is similar to 9 times higher than that of pure TiO2 nanoparticles (similar to 23 mu molh(-1)g(-1)). This report provides a potential strategy to overcome mass transfer limitation and achieve a high conversion efficiency in PNF.
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