Guaiacol hydrodeoxygenation in hydrothermal conditions using N-doped reduced graphene oxide (RGO) supported Pt and Ni catalysts: Seeking for economically viable biomass upgrading alternatives

Herein we present an innovative route for model biomass compounds upgrading via H-2-free hydrodeoxygenation (HDO) reactions. The underlaying idea is to implement a multifunctional catalyst able to activate water and subsequently use in-situ generated hydrogen for the HDO process. In this sense we have developed a series of effective Ni and Pt based catalysts supported on N-promoted graphene decorated with ceria. The catalyst reached commendable conversion levels and selectivity to mono-oxygenated compounds considering the very challenging reaction conditions. Pt outperforms Ni when the samples are tested as-prepared. However, Ni performance is remarkably boosted upon applying a pre-conditioning reductive treatment. Indeed, our NiCeO2/GOr-N present the best activity/selectivity balance and it is deemed as a promising catalyst to conduct the H-2-free HDO reaction. Overall, this proof-concept showcases an economically appealing mute for bio-compounds upgrading evidencing the key role of advanced catalysts for a low carbon future.

Automated summary

The study proposes an innovative route for upgrading biomass compounds through H-2-free hydrodeoxygenation reactions using a multifunctional catalyst. It demonstrates the superior performance of NiCeO2/GOr-N catalyst in terms of activity and selectivity balance, highlighting the key role of advanced catalysts in achieving a low carbon future.