Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 60, Issue 19, Pages 10608-10613Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202016703
Keywords
all-inorganic perovskite solar cells; charge transfer doping; interfacial charge extraction; long-term stability; two-dimensional materials
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Funding
- Guangdong Basic and Applied Basic Research Foundation [2020A1515110548]
- Postdoctoral Research Foundation of China [2020M683185]
- National Natural Science Foundation of China [61774139, 62004083, U1802257]
- Natural Science Foundation of Guangdong Province [2019B151502061, 2020A1515011123]
- Fundamental Research Funds for the Central Universities [21620348, 21618409, 21619311]
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By utilizing (NiCo)(1-y)FeyOx nanoparticle decorated graphene oxide (GO), the efficiency of all-inorganic CsPbIBr2 PSC was significantly improved, resolving the contradiction between charge extraction and localization. The top device exhibited excellent long-term stability under 10% relative humidity without encapsulation for over 70 days.
The precise regulation of interfacial charge distribution highly determines the power conversion efficiency of perovskite solar cells (PSCs). Herein, inorganic (NiCo)(1-y)FeyOx nanoparticle decorated graphene oxide (GO) is successfully demonstrated as a hole booster for all-inorganic CsPbIBr2 PSC free of precious metal electrode. Arising from the spontaneous electron transfer induced p-type doping of GO from edged oxygen-containing functional groups to (NiCo)(1-y)FeyOx, the best all-inorganic CsPbIBr2 PSC achieves an efficiency of 10.95 % under one standard sun owing to the eliminated paradox between charge extraction and charge localization in GO surface. Furthermore, the champion device exhibits an excellent long-term stability at 10 % relative humidity without encapsulation over 70 days because of the suppressed ions migration.
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