Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 363, Issue 10, Pages 2541-2545Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202100112
Keywords
palladium catalyst; Carbonylation; Benzyl chloride; Sulfonyl Chloride; Thioester
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Funding
- Natural Science Foundation of Zhejiang Province [LY21B020010]
- Fundamental Research Funds of Zhejiang Sci-Tech University [2020Q038]
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A convenient method for synthesizing thioesters has been developed using a palladium-catalyzed thiocarbonylation of benzyl chlorides with sulfonyl chlorides. By utilizing sulfonyl chlorides as an odorless sulfur source, various arylacetyl thioesters were produced in good yields. Additionally, W(CO)(6) played dual roles as both a solid CO surrogate and reductant in this process.
A convenient procedure for the synthesis of thioesters has been developed via a palladium-catalyzed thiocarbonylation of benzyl chlorides with sulfonyl chlorides. Various arylacetyl thioesters were produced in good yields by using sulfonyl chlorides as an odorless sulfur source. Furthermore, W(CO)(6) exhibited dual roles as both a solid CO surrogate and reductant here.
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