4.8 Review

Rare-Earth Incorporated Alloy Catalysts: Synthesis, Properties, and Applications

Journal

ADVANCED MATERIALS
Volume 33, Issue 16, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.202005988

Keywords

alloy materials; catalysis; energy conversion; rare earth

Funding

  1. National Natural Science Foundation of China [21522106, 21971117]
  2. 111 Project from China [B18030]
  3. National Key R&D Program of China [2017YFA0208000]
  4. State Key Laboratory of Rare Earth Resource Utilization [RERU2019001]
  5. Functional Research Funds for the Central Universities, Nankai University [ZB19500202]
  6. Beijing-Tianjin-Hebei Collaborative Innovation Project [63201058]
  7. Australian Research Council [DP190100295, LE190100014]
  8. ANU Futures Scheme [Q4601024]

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Alloying is an efficient methodology to improve the performance of metallic catalysts, rare-earth metal compounds can integrate the unique orbital structure and catalytic behavior of rare earth elements; these alloys provide an opportunity to tailor electronic properties, tune charged carrier transport, and enhance surface reactivity.
To improve the performance of metallic catalysts, alloying provides an efficient methodology to design state-of-the-art materials. As emerging functional materials, rare-earth metal compounds can integrate the unique orbital structure and catalytic behavior of rare earth elements into metallic materials. Such rare-earth containing alloy catalysts proffer an opportunity to tailor electronic properties, tune charged carrier transport, and synergize surface reactivity, which are expected to significantly improve the performance and stability of catalysis. Despite its significance, there are only few reviews on rare earth containing alloys or related topics. This review summarizes the composition, synthesis, and applications of rare earth containing alloys in the field of catalysis. Subsequent to comprehensively summarizing and constructively discussing the existing work, the challenges and possibilities of future research on rare-earth metal compound materials are evaluated.

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