4.8 Review

Core/Shell Metal Halide Perovskite Nanocrystals for Optoelectronic Applications

Journal

ADVANCED FUNCTIONAL MATERIALS
Volume 31, Issue 19, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202100438

Keywords

core; shell nanocrystals; metal halide perovskites; optical properties; optoelectronics; shell growth mechanisms

Funding

  1. Australian Research Council (ARC) Discovery Early Career Researcher Award [DE160100589]
  2. National Natural Science Foundation of China [61735004, 51675322]
  3. National Key Research and Development Program of China [2016YFB0401702]
  4. Shanghai Science and Technology Committee [19010500600]
  5. China Postdoctoral Science Foundation [2020M680054]
  6. Engineering and Physical Sciences Research Council [EP/P031684/1]
  7. Australian Research Council [DE160100589] Funding Source: Australian Research Council
  8. EPSRC [EP/P031684/1] Funding Source: UKRI

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Core/shell structured metal halide perovskite nanocrystals are a type of material with remarkable optical and electronic properties, with rapid development and significant advances in research in recent years. Enhancing the stability and optical performance of these materials is crucial for their applications in optoelectronic technologies. The review summarizes recent advances in core/shell structured perovskite nanocrystals, including band structures, shell classification, shell engineering approaches, and discussions on potential applications in different devices.
Core/shell structured metal halide perovskite nanocrystals (NCs) are emerging as a type of material with remarkable optical and electronic properties. Research into this field has been developing and expanding rapidly in recent years, with significant advances in the studies of the shell growth mechanism and in understanding of properties of these materials. Significant enhancement of both the stability and the optical performance of core/shell perovskite NCs are of particular importance for their applications in optoelectronic technologies. In this review, the recent advances in core/shell structured perovskite NCs are summarized. The band structures and configurations of core/shell perovskite NCs are elaborated, the shell classification and shell engineering approaches, such as perovskites and their derivative shells, semiconductor shell, oxide shell, polymer shell, etc. are reviewed, and the shell growth mechanisms are discussed. The prospective of these NCs in lighting and displays, solar cells, photodetectors, and other devices is discussed in the light of current knowledge, remaining challenges, and future opportunities.

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