4.8 Article

Electrostatic Jumping of Frost

Journal

ACS NANO
Volume 15, Issue 3, Pages 4669-4677

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsnano.0c09153

Keywords

condensation frosting; deicing; electrostatic force; electric polarization; ionic transport; jumping frost

Funding

  1. National Science Foundation [CBET-2034242]

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The study investigates the electrification of ice and reveals the surprising phenomenon of jumping frost dendrites. Through experimental observation and analytical and numerical modeling, the attractive force between frost dendrites and liquid was estimated, providing insights into charge separation in ice growth. The unexpected jumping frost event could serve as a model system for resolving long-standing questions in atmospheric physics and has potential applications in deicing technology.
The electrification of ice has been a subject of research since 1940, mostly in the context of charge generation in thunderstorms. This generation of electric charge is spontaneous, distinct from applying an external electric field to affect the diffusive growth of ice crystals. Here, we exploit the spontaneous electrification of ice to reveal a surprising phenomenon of jumping frost dendrites. We use side-view high-speed imaging to experimentally observe frost dendrites breaking off from mother dendrites and/or the substrate to jump out-of-plane toward an opposing polar liquid. Analytical and numerical models are then developed to estimate the attractive force between the frost dendrites and liquid, in good agreement with the experimental results. These models estimate the extent of charge separation within a growing sheet of frost, which is caused by mismatches in the mobilities of the charge carriers in ice. Our findings show that the unexpected jumping frost event can serve as a model system for resolving long-standing questions in atmospheric physics regarding charge separation in ice, while also having potential as a deicing construct.

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