Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 13, Issue 8, Pages 10131-10140Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.1c00565
Keywords
multivalent batteries; solid electrolyte interphase; zinc ion battery; Zn electrolyte; in situ Zn deposition; EQCM with dissipation
Funding
- Joseph P. Healey Research Grant from University of Massachusetts Boston
- Endowed Faculty Career Development Award from University of Massachusetts Boston
- MRI grant of the National Science Foundation [1919919]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1919919] Funding Source: National Science Foundation
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Multivalent chemistry offers benefits for developing energy storage technologies beyond lithium ion. Metallic zinc anodes are appealing for secondary ion batteries due to their high volumetric capacity at a low cost. However, the complex interfacial mass exchange at the Zn electrolyte/anode boundary and the dynamic progression of the solid electrolyte interphase (SEI) are still not fully understood. Critical differences were observed in SEI formation between nonaqueous and aqueous Zn electrolytes for reversible Zn deposition, with a disproportional loss of coulombs in the nonaqueous electrolyte suggesting in situ formation of an ionically permeable SEI layer.
Multivalent chemistry provides intriguing benefits of developing beyond lithium ion energy storage technologies and has drawn extensive research interests. Among the multivalent candidates, metallic zinc anodes offer an attractive high volumetric capacity at a low cost for designing the secondary ion batteries. However, the interfacial mass exchange at the Zn electrolyte/anode boundary is complicated. The least understood solid electrolyte interphase (SEI) occurs simultaneously with the reversible metal deposition, and its dynamic progression is unclear and difficult to capture. One major challenge to investigate such a dynamic interface is the lack of in situ analytical methods that offer direct mass transport information to reproduce the realistic battery operating conditions in an air-sensitive, nonaqueous electrolyte environment with a high iR drop. Work reported here reveals an in-depth analysis of the complex and dynamic SEI at the Zn electrolyte/electrode interface utilizing a multiharmonic quartz crystal microbalance with a dissipation method combined with the spectroscopic analysis. Key differences are observed for the SEI formation in the nonaqueous Zn(TFSI)(2) electrolyte in contrast to the aqueous ZnCl2 electrolyte for reversible Zn deposition. A large disproportional loss of coulombs relative to the gravimetric mass change is prominently observed at the initial electrochemical cycles in the nonaqueous Zn electrolyte, and results suggest an in situ formation of an ionically permeable SEI layer that is compositionally featured with a rich content of organic S and N components. Further overtone-dependent dissipation analysis implies the changes in viscoelasticity at the electrode interface during the early SEI formation in the nonaqueous Zn(TFSI)(2) electrolyte.
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