4.8 Article

One-Step Construction of a Hollow Au@Bimetal-Organic Framework Core-Shell Catalytic Nanoreactor for Selective Alcohol Oxidation Reaction

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 13, Issue 10, Pages 12463-12471

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.0c20445

Keywords

metal-organic frameworks; hierarchical design; hollow nanostructures; core-shell nanoreactor; heterogeneous catalysis

Funding

  1. National Natural Science Foundation of China (NSFC) [21501003, U1732272]
  2. State Key Laboratory of Tea Plant Biology and Utilization [SKLTOF20190116]
  3. DNL Cooperation Fund, CAS [DNL180201]
  4. Program for Excellent Talents in the University of Ministry of Education of China [gxyqZD2020008]
  5. National Undergraduate Training Programs for Innovation and Entrepreneurship of Anhui Agriculture University [202010364041]

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Hollow core-shell catalytic nanoreactors featuring bimetallic porous Zn/Ni-MOF-2 shell and tiny Au nanoparticle core were successfully constructed through a rare crystal-structure transformation strategy. These nanoreactors exhibit outstanding multifunctional catalysis for a broad range of alcohol oxidation under the green oxidant environment, showing excellent recyclability in selective alcohol oxidation. These findings may provide a promising platform for the general construction of various metal-organic framework-based hollow core-shell nanostructures and further highly augmented catalytic applications.
Hollow core-shell catalytic nanoreactors have received tremendous attention due to their high mass transfer in catalysis applications. Herein, we present a novel type of well-arranged, hollow core-shell nanoreactors featured with a bimetallic porous Zn/Ni-MOF-2 shell and a tiny Au nanoparticle core. The well-designed hollow Au@Zn/Ni-MOF-2 nanoreactors were constructed through the strategy of a facile one step from a rare crystal-structure transformation without any additional template. These nanoreactors exhibit outstanding multifunctional catalysis for a broad range of alcohol oxidation under the green oxidant environment. Moreover, such hollow nanoreactors show excellent recyclability toward the selective alcohol oxidation. These findings might provide a promising platform for a general construct of various metal-organic framework-based hollow core-shell nanostructures and further highly augmented catalytic applications.

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