Journal
ELECTROCHIMICA ACTA
Volume 208, Issue -, Pages 148-155Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2016.05.026
Keywords
Porous nanosheets; Flower-like architecture; Electrochemical property; Lithium ion battery; Lithium oxygen battery
Categories
Funding
- 973 Project of China [2011CB935901]
- National Nature Science Foundations of China [21471090]
- Shandong Provincial Natural Science Foundation for Distinguished Young Scholar [JQ201205]
- Taishan Scholar Program of Shandong Province [ts2015110004]
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Hierarchical CuCo2O4 microflowers (CCFs) self-assembled by thin and porous nanosheets were synthesized by a simple solvothermal reaction followed by a low-temperature calcination. The porous nanosheets not only shorten the Li-ion diffusion distances and tolerate the volume variation upon cycling, but also enhance the transportation of oxygen and Li+ ions, and have abundance of active sites on the surface. Thus, it has been explored as the superior anode material in Li-ion batteries and as the cathode catalyst in Li-O-2 batteries. Both of applications exhibit the remarkable electrochemical properties. In lithium ion batteries, CuCo2O4 micro-flowers deliver a specific lithium storage capacity of 871 mA h g(-1), after 300 cycles at 100 mA g(-1). Even at a high rate of 1 A g(-1), the reversible capacity of the CuCo2O4 microflowers still remains at 612 mA h g(-1) after 500 cycles. In Li-O-2 batteries, CuCo2O4 microflowers as the cathode catalyst last 120 cycles, much longer than highly aggregated CuCo2O4 and pure carbon. (C) 2016 Elsevier Ltd. All rights reserved.
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