Journal
ELECTROCHIMICA ACTA
Volume 218, Issue -, Pages 216-227Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2016.09.122
Keywords
TiO2/RGO/Ni(OH)(2); Ni foam; Hydrothermal; Supercapacitor
Categories
Funding
- National Natural Science Foundation of China [20504026]
- Shanghai Natural Science Foundation [13ZR1411900]
- Shanghai Key Laboratory Project [08DZ2230500]
- Shanghai Leading Academic Discipline Project [B502]
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A facile one-step hydrothermal process is employed to synthesize a TiO2/RGO/Ni(OH)(2) (reduced graphene oxide, RGO) composite on nickel foam (NF) by means of an in-situ growth route. In this case, NF acts as support, nickel source of Ni(OH)(2), and supplement reductant of GO. For comparison, RGO nanosheets serve as nano-sized flexible support for connecting TiO2 and Ni(OH)(2) blocks, which improves the electron transfer and alleviates the volume changes during the repeated charge/discharge process thanks to its high conductivity and mechanical properties. Besides, P25 (commercial TiO2 consisting of 80% anatase and 20% rutile) serves as TiO2 source, at different GO/P25 ratio of 1%, 2%, 5%, 10% and 20%. Electrochemical performances of TiO2/RGO/Ni(OH)(2)/NF electrode were evaluated by using cyclic voltammetry (CV), galvanostatic charge/discharge tests (GCD) and electrochemical impedance spectroscopy (EIS) in 1 M KOH electrolyte. The TiO2/RGO/Ni(OH)(2)/NF electrode exhibited significantly enhanced capacitive performance when the weight ratio of GO/P25 was 10%. It delivered high capability of 4342 mF cm(-2) at a current density of 5 mA cm(-2) (374.3 F g(-1) at 0.43 A g(-1)), and excellent charge-discharge cycling stability with 93.75% capacitance retention after 2000 cycles. An asymmetric supercapacitor (ASC) device consisting of this TiO2/RGO/Ni(OH)(2)/NF and an AC negative electrode was assembled. (C) 2016 Elsevier Ltd. All rights reserved.
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