4.6 Review

Recent advances on the use of active anodes in environmental electrochemistry

Journal

CURRENT OPINION IN ELECTROCHEMISTRY
Volume 27, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.coelec.2021.100689

Keywords

Active anodes; Metal mixed oxides (MMOs); Electrocatalysis; RuO2; IrO2

Funding

  1. FAPESP [2017/101180, 2017/20444-1]
  2. FAPEMIG
  3. CNPq [310027/2018-7, 307836/2018-5]

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Active anode materials, particularly those containing Ru and/or Ir oxides, are widely used in environmental electrochemistry for wastewater treatment. Recent studies have focused on enhancing mineralization capacity and producing free chlorine species for indirect organic reduction.
Active anodes, especially those consisting of metal mixed oxides (MMOs) containing Ru and/or Ir oxides, have been applied in the treatment of wastewater, especially when chloride ions are present. Their characteristics continuously drive the study of applications of these materials, be they in the degradation of different organic molecules, the preparation of new electrode materials and in the association of various processes to increase pollutant removal. Thus, this brief review aims to present some of the recent advances in the application of active anode materials in environmental electrochemistry. Focussing on the 2018-2020 period, it is possible to note many applied studies, using commercially available materials, covering a wide range of target pollutants. Still other studies aim to modify the catalyst surfaces to increase the mineralization capacity, and the use of these anodes in the production of free chlorine species to mediate indirect organic reduction is observed.

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