4.6 Article

Generating Bulk Nanobubbles in Alcohol Systems

Journal

ACS OMEGA
Volume 6, Issue 4, Pages 2873-2881

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsomega.0c05222

Keywords

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Funding

  1. National Natural Science Foundation of China [11975297, 11674344]
  2. Key Research Program of Frontier Sciences, CAS [QYZDJ-SSW-SLH019]

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This study confirmed the generation of bulk nanobubbles in pure organic solutions, with the optimized parameters allowing the bubbles to stably exist for several hours in alcohol systems. These findings open up new opportunities for improving gas-liquid mass transfer efficiency in the chemical industry.
Bulk nanobubbles (NBs) have attracted wide attention due to their peculiar physicochemical properties and great potential in applications in various fields. However, so far there are no reports on bulk NBs generated in pure organic systems, which we think is very important as NBs would largely improve the efficiency of gas-liquid mass transfer and facilitate chemical reactions to take place. In this paper, we verified that air and N-2 NBs could be generated in a series of alcohol solutions by using various methods including acoustical cavitation, pressurization-depressurization, and vibration. The experiments proved that NBs existed in alcohol solutions, with a highest density of 5.8 X 10(7) bubble/mL in propanol. Our results also indicated that bulk NBs could stably exist for at least hours in alcohol systems. The parameters in generating NBs in alcohols were optimized. Our findings open up an opportunity for improving gas-liquid mass transfer efficiency in the field of the chemical industry.

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