Iron phosphide as negative electrode material for Na-ion batteries

Iron phosphides, FeP2 and FeP4, have been synthesized and characterized for the application to non-aqueous Na-ion battery. FeP2 shows no significant electrochemical reactivity in Na-cell. However, FeP4 composite electrode with sodium polyacrylate binder delivers a reversible capacity of 1137 mAh.g(-1) and a Coulombic efficiency of 84.0% during the first cycle under a current density of 89 mA.g(-1). The high capacity is maintained for 30 cycles. Moreover, FeP4 composite electrode presents a good rate capability. Although the sodiation mechanism of FeP4 has not been fully understood, FeP4 is a new promising negative electrode material for Na-ion batteries with both high-power and high-energy densities. (C) 2016 Elsevier B.V. All rights reserved.