4.6 Article

Poly(anthraquinonyl sulfide) cathode for potassium-ion batteries

Journal

ELECTROCHEMISTRY COMMUNICATIONS
Volume 71, Issue -, Pages 5-8

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2016.07.011

Keywords

Potassium-ion batteries; Organic material; Cathode; Polymer

Funding

  1. National Science Foundation [CBET-1551693, CMMI-1400261]
  2. Office of Naval Research [N00014-13-1-0543]
  3. Directorate For Engineering
  4. Div Of Chem, Bioeng, Env, & Transp Sys [1551693] Funding Source: National Science Foundation
  5. Div Of Civil, Mechanical, & Manufact Inn
  6. Directorate For Engineering [1400261] Funding Source: National Science Foundation

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Potassium-ion batteries (KIBs) are a promising sustainable energy storage technology due to the high abundance and low cost of potassium. Carbon anode materials for KIBs have seen great successes, but the development of cathode materials is yet to catch up. In this study, poly(anthraquinonyl sulfide) (PAQS) is evaluated as a cathode material for KIBs. It exhibits a high reversible capacity of 200 mAh/g, which is the highest value for a potassium storage cathode material. The cell shows two slopes averaged at 2.1 and 1.6 V vs. K+/K. It shows a good cycling performance with the capacity retention of 75% after 50 cycles at a rate of C/10. These preliminary results indicate that PAQS is a promising cathode material for KIBs. (C) 2016 Published by Elsevier B.V.

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