Journal
CHEMISTRYSELECT
Volume 5, Issue 47, Pages 15010-15014Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.202004130
Keywords
alkyne-azide; copper; covalent organic frameworks; click reaction; porous material
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Funding
- Natural Science Foundation of Hainan Province [519QN186, 2019RC250]
- National Natural Science Foundation of China [21965011]
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Functional modification of the covalent organic frameworks (COFs) has become an efficient strategy to expand its applications in various fields. In this investigation, an imine linked T-D COF has been synthesized via solvothermal method using 2,4,6-tris(4-aminophenyl)pyridine (TAPP) and 2,6-dihydroxynaphthalene-1,5-dicarbaldehyde (DHNDA) as building blocks. While synthesizing T-D COF, hydroxyl groups are strategically introduced to the adjacent sites of -C=N- bonds in the framework. Such a special structure enables a strong coordination between the loaded copper metal ion and the hydroxyl groups together with imine bounds in the COF layered structure. The obtained copper-containing COF, (Cu@T-D COF) hybrid material was used as an efficient heterogeneous catalyst for the alkyne-azide click chemistry reactions and showed excellent catalytic activity in methanol/water medium. Furthermore, this Cu@T-D COF is stable and easily recycled and reused without loss of its catalytic activity.
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