Journal
CHEMISTRYSELECT
Volume 5, Issue 45, Pages 14484-14509Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.202003341
Keywords
Cyclopentene-1; 3-diones; Desymmetrization; Asymmetric synthesis; Alkylation; Cycloaddition
Categories
Funding
- Department of Chemistry, NIT Jamshedpur
- SERB-DST
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Desymmetrization of prochiral cyclopentene-1,3-diones for the synthesis of various natural products and moieties of pharmaceutically active compounds, is a very challenging and competitive area of research in organic synthesis now a days. It is a very powerful strategy to provide quaternary stereocenter having different functionality, which is very difficult to install by other C-C bond-forming methods. This review describes an elaborative discussion of desymmetrization of cyclopentene-1,3-diones (racemic and asymmetric) via different alkylation, arylation, amidation and cycloaddition process for the last decades.
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