Synthesis of Hydronium-Potassium Jarosites: The Effect of pH and Aging Time on Their Structural, Morphological, and Electrical Properties

Structural and morphological properties of hydronium-potassium jarosite microstructures were investigated in this work, and their electrical properties were evaluated. All the microstructures were synthesized at a very low temperature of 70 degrees C with a reduced reaction time of 3 h. An increase in the pH from 0.8 to 2.1 decreased the particle sizes from 3 mu m to 200 nm and an increase in the aging time from zero, three, and seven days resulted in semispherical, spherical, and euhedral jarosite structures, respectively. The Rietveld analysis also confirmed that the amount of hydronium substitution by potassium in the cationic site increased with an increase in pH. The percentages of hydronium jarosite (JH)/potassium jarosite (JK) for pH values of 0.8, 1.1, and 2.1 were 77.72/22.29%, 82.44/17.56%, and 89.98/10.02%, respectively. Microstructures obtained in this work were tested as alternative anode materials and the voltage measured using these electrodes made with hydronium-potassium jarosite microstructures and graphite ranged from 0.89 to 1.36 V. The results obtained in this work show that with reduced particle size and euhedral morphology obtained, modified jarosite microstructures can be used as anode materials for improving the lifetime of lithium-ion batteries.

Automated summary

This study investigated the structural and morphological properties of hydronium-potassium jarosite microstructures and evaluated their electrical properties. The results showed that as the pH increased, the particle size decreased and morphology changed, and the amount of hydronium substitution by potassium also increased. By using the microstructures as electrode materials in combination with graphite, a higher voltage range was obtained.