A Mineral By-Product from Gasification of Poultry Feathers for Removing Cd from Highly Contaminated Synthetic Wastewater

Ash from poultry feather gasification was investigated as an adsorbent for Cd removal from synthetic wastewater under a range of operational conditions: initial pH (2-8) and salinity (8-38 mS/cm) of wastewater, ash dosage (2.5-50 g/L), Cd concentration (25-800 mg/L) and contact time (5-720 min). The ash was highly alkaline and had low surface area and micropores averaging 1.12 nm in diameter. Chemical/mineralogical analysis revealed a high content of P2O5 (39.9 wt %) and CaO (35.5 wt %), and the presence of calcium phosphate, hydroxyapatite and calcium. It contained only trace amounts of heavy metals, BTEX, PAHs and PCBs, making it a safe mineral by-product. Cd adsorption was described best with Langmuir and pseudo-second order models. At pH 5, an ash dosage of 5 g/L, 40 min contact time and 100 mg Cd/L, 99% of Cd was removed from wastewater. The salinity did not affect Cd sorption. The maximum adsorption capacity of Cd was very high (126.6 mg/g). Surface precipitation was the main mechanism of Cd removal, possibly accompanied by ion exchange between Cd and Ca, coprecipitation of Cd with Ca-mineral components and Cd complexation with phosphate surface sites. Poultry ash effectively removes high concentrations of toxic Cd from wastewater.