4.5 Article

Catalytic Degradability of p-Nitrophenol Using Ecofriendly Silver Nanoparticles

Journal

METALS
Volume 10, Issue 12, Pages -

Publisher

MDPI
DOI: 10.3390/met10121661

Keywords

anthropogenic; bioreductant; environmental remediation; heterogeneous catalysis; plant extract; p-nitrophenol; silver nanoparticles

Funding

  1. National Research Foundation of Korea (NRF) - Ministry of Education [NRF-2020R1I1A3065371]
  2. Priority Research Centers Program through the National Research Foundation of Korea (NRF) - Ministry of Education [NRF-2018R1A6A1A03025526]
  3. National Research Foundation of Korea [5199991714396] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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In an effort to produce non-toxic and economically viable green protocols for waste water treatment, researchers are actively involved to develop versatile and effective silver nanoparticles (SNPs) as nano-catalyst from bio-based techniques. Since, p-nitrophenol (PNP) is one of the anthropogenic contaminants, considerable attention has been focused in catalytic degradability of PNP in wastewater treatment by curtailing serious effect on aquatic fauna. Ingestion of contaminants by aquatic organisms will not only affect the aquatic species but is also a potential threat to human health, especially if the toxic contaminants are involved in food chain. In this short report, we provided a comprehensive insight on few remarkable nanocatalysts especially based on SNPs and its biopolymer composites synthesized via ecofriendly green route. The beneficiality and catalytic performance of these silver nanocatalysts are concisely documented on standard model degradation reduction of PNP to p-aminophenol (PAP) in the presence of aqueous sodium borohydride. The catalytic degradation of PNP to PAP using SNPs follows pseudo first order kinetics involving six-electrons with lower activation energy. Furthermore, we provided a list of highly effective, recoverable, and economically viable SNPs, which demonstrated its potential as nanocatalysts by focusing its technical impact in the area of water remediation.

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