Journal
CATALYSTS
Volume 11, Issue 1, Pages -Publisher
MDPI
DOI: 10.3390/catal11010022
Keywords
microalgal biomass; thermochemical conversion; catalytic upgrading; liquid fuels; hydrothermal liquefaction; pyrolysis; gasification
Categories
Funding
- Sapienza University of Rome (Italy)
- Gen Foundation
- UFPS internal Research funding [FINU 27-2019]
- Newton Fund Institutional Links [527624805]
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Microalgal biomass has gained importance in various industries due to its rapid growth and high carbon-fixing efficiency. Thermochemical processes are effective in obtaining biofuels, but direct conversion results in high heteroatom content, leading to the emergence of catalyst-based solutions for increased biocrude production. This paper aims to review recent developments in catalyst-mediated conversion of algal biomass, focusing on optimal yield of algal-based biofuels through pyrolysis and HTL.
Over the last decades, microalgal biomass has gained a significant role in the development of different high-end (nutraceuticals, colorants, food supplements, and pharmaceuticals) and low-end products (biodiesel, bioethanol, and biogas) due to its rapid growth and high carbon-fixing efficiency. Therefore, microalgae are considered a useful and sustainable resource to attain energy security while reducing our current reliance on fossil fuels. From the technologies available for obtaining biofuels using microalgae biomass, thermochemical processes (pyrolysis, Hydrothermal Liquefaction (HTL), gasification) have proven to be processed with higher viability, because they use all biomass. However, due to the complex structure of the biomass (lipids, carbohydrates, and proteins), the obtained biofuels from direct thermochemical conversion have large amounts of heteroatoms (oxygen, nitrogen, and sulfur). As a solution, catalyst-based processes have emerged as a sustainable solution for the increase in biocrude production. This paper's objective is to present a comprehensive review of recent developments on the catalyst-mediated conversion of algal biomass. Special attention will be given to operating conditions, strains evaluated, and challenges for the optimal yield of algal-based biofuels through pyrolysis and HTL.
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