Journal
ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 10, Issue 1, Pages 91-128Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.202000582
Keywords
Se-77 NMR; organoselenium; reaction mechanism; selenium-catalysis
Categories
Funding
- Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior - Brasil (CAPES) [001]
- FAPERGS [PqG 17/2551-0000987-8]
- CNPq
- FINEP
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This review article focuses on organic synthesis from the perspective of selenium-77 nuclear magnetic resonance (NMR) spectroscopy. It briefly discusses different types of organic reactions, incorporating mechanisms through observable intermediates and by-products by Se-77 NMR. The Se-77 NMR experiments provide structural characterization and new insights for organic reactions, offering a convenient and versatile route for the development of synthetic organoselenium compounds.
This review article deals with organic synthesis from the perspective of selenium-77 nuclear magnetic resonance (NMR) spectroscopy. Different types of organic reactions are briefly discussed, incorporating mechanism aspects through Se-77 NMR observable intermediates and by-products. The Se-77 NMR experiments are demonstrated in terms of structural characterization and new insights for organic reactions. The ability to visualize different molecules in a reaction mixture provides a facile and versatile route for the development of synthetic organoselenium compounds. Thus, the review describes the strategies accomplished mainly in the past five years in the syntheses and applications of the organoselenium compounds, focusing on Se-77 NMR spectroscopy.
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