Journal
ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 10, Issue 2, Pages 375-381Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.202000612
Keywords
arsenic; phosphorus; selective coordination; template ligand; heterodinuclear complex
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Funding
- JSPS KAKENHI [19H04577, 20H02812]
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By designing a novel ligand with a template based on the difference in coordination ability between phosphorus and arsenic, precise arrangement of Lewis acids was achieved on the template ligand.
Phosphorus and arsenic have different coordination ability to Lewis acids, though they belong to 15 group. Utilizing the difference, we designed a novel ligand, (p-(diphenylarsino)phenyl)diphenylphosphine, in which diphenylphosphine and diphenylarsine units are combined through a p-phenylene linker, as a template to arrange Lewis acids. The phosphorus atom exhibited superior coordination ability to the arsenic one. NMR studies revealed that BH3, AuCl, and PtCl2 were preferentially coordinated by the phosphorus atom. Sequential addition of these Lewis acids realized precise arrangement on the template ligand.
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