Journal
POLYMERS
Volume 13, Issue 2, Pages -Publisher
MDPI
DOI: 10.3390/polym13020276
Keywords
epoxidized natural rubber; ENR; silica nanocomposites; time-resolved mechanical spectroscopy; rheological behavior; gelation
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The rheological behavior of an epoxidized natural rubber (ENR) nanocomposite containing silica particles was studied using time-resolved mechanical spectroscopy. Two major events were identified: absorption of rubber macromolecules onto silica surface and gelation resulting in changes in rheological behavior. These events were quantified using parameters related to storage and loss modulus components.
The rheological behavior of an epoxidized natural rubber (ENR) nanocomposite containing 10 wt.% of silica particles was examined by time-resolved mechanical spectroscopy (TRMS), exploiting the unique capability of this technique for monitoring the time-dependent characteristics of unstable polymer melts. The resulting storage modulus curve has revealed a progressive evolution of the elastic component of the composite, associated with slower relaxations of the ENR macromolecular chains. Two major events were identified and quantified: one is associated with the absorption of the epoxidized rubber macromolecules onto the silica surface, which imposes further restrictions on the motions of the chains within the polymer phase; the second is related to gelation and the subsequent changes in rheological behavior resulting from the simultaneous occurrence cross-linking and chain scission reactions within the ENR matrix. These were quantified using two parameters related to changes in the storage and loss modulus components.
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