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A Review of the Polymer for Cryogenic Application: Methods, Mechanisms and Perspectives

Journal

POLYMERS
Volume 13, Issue 3, Pages -

Publisher

MDPI
DOI: 10.3390/polym13030320

Keywords

polymer; modification; cryogenic properties; liquid oxygen compatibility

Funding

  1. National Key Research and Development Program of China [2018YFA0702800]
  2. National Natural Science Foundation of China [11902063, 11972106, 11772075, U1837205]
  3. Fundamental Research Funds for the Central Universities [DUT16ZD214, DUT19ZD101, DUT19JC32]
  4. Shanghai Aerospace Science and Technology Innovation Fund Project [SAST2018-016]
  5. Postdoctoral Science Foundation of China [2019M661093]

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This paper reviews the application of polymer-based composites at cryogenic conditions, focusing on the research developments of thermoset and thermoplastic polymers. It provides a comprehensive overview of the cryogenic performance of various polymers and proposes future research directions for practical applications in aerospace.
Recently, the application of polymer-based composites at cryogenic conditions has become a hot topic, especially in aerospace fields. At cryogenic temperature, the polymer becomes more brittle, and the adverse effect of thermal stress induced by temperature is more remarkable. In this paper, the research development of thermoset and thermoplastic polymers for cryogenic applications are all reviewed. This review considers the literature concerning: (a) the cryogenic performance of modified thermoset polymers and the improving mechanisms of the reported modification methods; (b) the cryogenic application potential of some commercial thermoplastic polymers and the cryogenic performance of modified thermoplastic polymers; (c) the recent advance in the use of polymer for special cryogenic environment-liquid oxygen. This paper provides a comprehensive overview of the research development of the polymer for cryogenic application. Moreover, future research directions have been proposed to facilitate its practical applications in aerospace.

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