Electrolyte Concentration Regulation Boosting Zinc Storage Stability of High-Capacity K0.486V2O5 Cathode for Bendable Quasi-Solid-State Zinc Ion Batteries

Vanadium-based cathodes have attracted great interest in aqueous zinc ion batteries (AZIBs) due to their large capacities, good rate performance and facile synthesis in large scale. However, their practical application is greatly hampered by vanadium dissolution issue in conventional dilute electrolytes. Herein, taking a new potassium vanadate K0.486V2O5 (KVO) cathode with large interlayer spacing (similar to 0.95 nm) and high capacity as an example, we propose that the cycle life of vanadates can be greatly upgraded in AZIBs by regulating the concentration of ZnCl2 electrolyte, but with no need to approach water-in-salt threshold. With the optimized moderate concentration of 15 m ZnCl2 electrolyte, the KVO exhibits the best cycling stability with similar to 95.02% capacity retention after 1400 cycles. We further design a novel sodium carboxymethyl cellulose (CMC)-moderate concentration ZnCl2 gel electrolyte with high ionic conductivity of 10.08 mS cm(-1) for the first time and assemble a quasi-solid-state AZIB. This device is bendable with remarkable energy density (268.2 Wh kg(-1)), excellent stability (97.35% after 2800 cycles), low self-discharge rate, and good environmental (temperature, pressure) suitability, and is capable of powering small electronics. The device also exhibits good electrochemical performance with high KVO mass loading (5 and 10 mg cm(-2)). Our work sheds light on the feasibility of using moderately concentrated electrolyte to address the stability issue of aqueous soluble electrode materials.

Automated summary

By regulating the concentration of ZnCl2 electrolyte, the cycle life of Vanadates in AZIBs can be greatly improved without the need to approach the water-in-salt threshold. Additionally, a novel CMC-ZnCl2 gel electrolyte with high ionic conductivity was designed for the first time, enabling the assembly of a quasi-solid-state AZIB with excellent stability and energy density.