4.6 Article

Stable Superhydrophobic Aluminum Surfaces Based on Laser-Fabricated Hierarchical Textures

Journal

MATERIALS
Volume 14, Issue 1, Pages -

Publisher

MDPI
DOI: 10.3390/ma14010184

Keywords

single-and multi-scale textures; direct laser interference patterning; direct laser writing; superhydrophobicity; aluminum 1050

Funding

  1. German Research Foundation (German: Deutsche Forschungsgemeinschaft DFG) [323477257]
  2. German Research Foundation (DFG) under Excellence Initiative program by the German federal and state government to promote top-level research at German universities
  3. Alexander von Humboldt Foundation

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This study explored the fabrication methods of laser-microtextured surfaces and their impact on the characteristics of aluminum. Experimental analysis revealed the influence of different laser processing parameters on the surface topography. The results demonstrated that laser-textured surfaces exhibit excellent superhydrophobic properties and provide protection for smaller features under tribological conditions.
Laser-microtextured surfaces have gained an increasing interest due to their enormous spectrum of applications and industrial scalability. Direct laser interference patterning (DLIP) and the well-established direct laser writing (DLW) methods are suitable as a powerful combination for the fabrication of single (DLW or DLIP) and multi-scale (DLW+DLIP) textures. In this work, four-beam DLIP and DLW were used independently and combined to produce functional textures on aluminum. The influence of the laser processing parameters, such as the applied laser fluence and the number of pulses, on the resulting topography was analyzed by confocal microscopy and scanning electron microscopy. The static long-term and dynamic wettability characteristics of the laser-textured surfaces were determined through water contact angle and hysteresis measurements, revealing superhydrophobic properties with static contact angles up to 163 degrees and hysteresis as low as 9 degrees. The classical Cassie-Baxter and Wenzel models were applied, permitting a deeper understanding of the observed wetting behaviors. Finally, mechanical stability tests revealed that the DLW elements in the multi-scale structure protects the smaller DLIP features under tribological conditions.

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