Metal-Free Ceria Catalysis for Selective Hydrogenation of Crotonaldehyde

Selective hydrogenation of alpha,beta-unsaturated aldehydes to unsaturated alcohols is important for the synthesis of fine chemicals, yet very challenging. Herein, we reported a metal-free CeO2 nanorods (rCeO(2)) catalyst for gas-phase transformation of crotonaldehyde to crotyl alcohol with the highest selectivity of 93.2% at 323 K. Compared to CeO2 nanocubes and nanopolydra, r-CeO2 shows a much higher crotyl alcohol production rate, comparable turnover frequency to those of noble-metalbased catalysts, and very high crotyl alcohol selectivity. This can be associated with a relatively high density of surface oxygen vacancies on rCeO(2), which constructs the solid frustrated Lewis pair sites with enhanced heterolytic H-2 dissociation and preferred crotonaldehyde adsorption via the C=O bond. However, a further reduction of r-CeO2 by H-2 was observed to be unfavorable with regard to both catalytic activity and selectivity, because of the emergence of crotonaldehyde adsorption via the C=C bond. These findings provide a potential approach to fabricate high-performance and low-cost catalysts for selective hydrogenation of alpha,beta-unsaturated aldehydes to unsaturated alcohols using bare CeO2 with a rigid surface structure design.