Journal
NATURE COMMUNICATIONS
Volume 11, Issue 1, Pages -Publisher
NATURE PORTFOLIO
DOI: 10.1038/s41467-020-19683-z
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Funding
- Chinese Academy of Sciences [QYZDJSSW-SLH044]
- National Natural Science Foundation of China [21890734, 21890730, 21861132002, 21971247]
- Youth Innovation Promotion Association of CAS [2019036]
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Different from molecular level topology, the development of supramolecular topology has been limited due to a lack of reliable synthetic methods. Here we describe a supramolecular strategy of accessing Mobius strip, a fascinating topological object featured with only a single edge and single side. Through bending and cyclization of twisted nanofibers self-assembled from chiral glutamate amphiphiles, supramolecular nano-toroids with various twist numbers were obtained. Electron microscopic techniques could clearly identify the formation of Mobius strips when twist numbers on the toroidal fibers are odd ones. Spectroscopic and morphological analysis indicates that the helicity of the Mobius strips and nano-toroids stems from the molecular chirality of glutamate molecules. Therefore, M- and P-helical Mobius strips could be formed from L- and D-amphiphiles, respectively. Our experimental results and theoretical simulations may advance the prospect of creating chiral topologically complex structures via supramolecular approach. Different to exploring molecular topology, the development of supramolecular topology has been limited due to a lack of reliable synthetic methods. Here, the authors describe a supramolecular strategy to access Mobius strips through bending and cyclization of twisted nanofibers self-assembled from chiral glutamate amphiphiles.
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