Journal
SCIENCE OF THE TOTAL ENVIRONMENT
Volume 753, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.scitotenv.2020.142072
Keywords
Polyhalogenated carbazoles; Emerging organic contaminants; South China Sea; Sediment; Persistent organic pollutants
Categories
Funding
- National Natural Science Foundation of China [21876142]
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The study revealed that the concentration of PHCs in sediments of the northern South China Sea is mainly influenced by the organic carbon content and water depth, with different PHCs showing different correlations. The analysis of sediment cores also showed that the congener profiles and concentrations of PHCs have remained stable over the past century.
Polyhalogenated carbazoles (PHCs) have been frequently detected in various environments and have gained increasing attention due to their dioxin-like toxicity. In this study, 28 surface sediments and three sediment cores were collected from the northern South China Sea (SCS) to investigate the spatial and temporal distribution trends of PHCs. The total concentrations of PHCs in the surface sediments ranged from 0.25 ng/g to 3.10 ng/g, with a median concentration of 1.50 ng/g. The composition profiles of PHCs in the surface sediments were dominated by 3,6-dichlorocarbazole (36-CCZ), 3,6-dibromocarbazole (36-BCZ), and 1,3,6,8-tetrabromocarbazole (1368-BCZ). The total organic carbon (TOC) based concentrations of 36-CCZ, 1-bromo-3,6-dichlorocarbazole, 1,3,6,8-tetrachlorocarbazole, and 1368-BCZ showed significant positive correlation with water depth (r = 0.58-0.88, p values < 0.01). On the contrary, the TOC based concentration of 2,3,6,7-tetrachlorocarbazole displayed a significant negative correlation with the water depth (r=-0.52, p < 0.01). However, no significant correlation was observed for 3-chlorocarbazole, 36-BCZ, and 1,3,6-tribromocarbazole (p values > 0.05). PHCs in sediment cores showed that congener profiles and concentrations of PHCs remained largely stable throughout the 1890s and 2010s. In addition, all the detected PHCs displayed a significant positive correlation with TOC content of the sediments. These unique spatial and temporal distribution patterns suggest that both terrigenous and natural marine sources contributed the observed PHCs in sediments of the northern SCS. (C) 2020 Elsevier B.V. All rights reserved.
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