4.5 Article

'In water' exploration of Alpinia zerumbet-fabricated CuO NPs in the presence of NaPTS at room temperature: green synthesis of 1,8-dioxooctahydroxanthene derivatives

Journal

RESEARCH ON CHEMICAL INTERMEDIATES
Volume 47, Issue 3, Pages 1221-1237

Publisher

SPRINGER
DOI: 10.1007/s11164-020-04351-0

Keywords

Alpinia zerumbet; CuO NPs; NaPTS; Room temperature

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This study investigated the biogenic synthesis of copper oxide nanoparticles from Alpinia zerumbet leaf extract, which showed efficient reactivity, stability, and recyclability in a water solution of NaPTS hydrotrope. The catalytic system formed by CuO NPs fabricated from A. zerumbet leaf extract in combination with NaPTS proved to be the best in terms of yield and reaction time in water at room temperature.
The biogenic synthesis of copper oxide nanoparticles (CuO NPs) from the leaf extract of Alpinia zerumbet was investigated in this protocol. The basic nature of A. zerumbet leaf extract helps in CuO NPs synthesis. The catalytic activity of A. zerumbet-fabricated CuO NPs is explored in water at room temperature only in the presence of NaPTS hydrotrope. The green catalytic protocol is investigated via synthesis of 1,8-dioxooctahydroxanthene. The biogenic leaf extract fabricated CuO NPs are efficiently reactive, stable and recyclable in aqueous solution of sodium p-toluenesulfonate (NaPTS) hydrotrope. CuO/NaPTS proved to be the best catalytic system as synergistic nanotrope in terms of yield and time of reaction in water at room temperature. The green synthetic approach of CuO NPs, greener medium, easy workup and proficient recyclability are advantages in the said protocol. This is first time report of catalytic activity of biogenic CuO NPs in water at room temperature in the presence of NaPTS.

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