4.7 Article

Sensing mechanism of Ag/α-MoO3 nanobelts for H2S gas sensor

Journal

RARE METALS
Volume 40, Issue 6, Pages 1545-1553

Publisher

NONFERROUS METALS SOC CHINA
DOI: 10.1007/s12598-020-01647-3

Keywords

Ag/alpha-MoO3; Nanobelt; Gas sensor; Hydrogen sulfide; Sensing mechanism

Funding

  1. National Natural Science Foundation of China [21771060, 61271126]
  2. International Science and Technology Cooperation Program of China [2016YFE0115100]
  3. Heilongjiang Educational Department [RCYJTD201903]
  4. Heilongjiang Touyan Innovation Team Program

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The sensing mechanism remains a major issue in gas sensor technology, with the study of sensing mechanisms providing better ideas for sensor material design and improving gas-sensing performance. In this study, Ag was loaded into alpha-MoO3 nanobelts to improve the material's selectivity to hydrogen sulfide, resulting in enhanced gas sensing properties. The 5 wt% Ag/alpha-MoO3 sensor showed a response of 225 to 100 x 10(-6) hydrogen sulfide with a detection limit of 100 x 10(-9), showcasing the effectiveness of the sensing mechanism.
Sensing mechanism is still a big problem in the field of gas sensor. In-depth study of the sensing mechanism can provide better ideas for the design of sensing materials, and it is also more conducive to the improvement in gas-sensing performance. In this work, Ag/alpha-MoO3 material was obtained by loading Ag in alpha-MoO3 nanobelts prepared by hydrothermal method. The material was characterized by field electron scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Comparing the gas sensing properties of alpha-MoO3 and Ag/alpha-MoO3, it is found that Ag effectively improves the selectivity of the material to H2S at 133 degrees C. The response of the 5 wt% Ag/alpha-MoO3 sensor to 100 x 10(-6) hydrogen sulfide (H2S) is 225 and the detection limit is 100 x 10(-9). The sensing mechanism was verified by gas chromatography and mass spectrometer (GC-MS), XPS and Fourier transform infrared spectroscopy (FTIR).

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