4.3 Review

Improved Designs of Multifunctional Covalent-Organic Frameworks: Hydrogen Storage, Methane Storage, and Water Harvesting

Journal

MINI-REVIEWS IN ORGANIC CHEMISTRY
Volume 18, Issue 8, Pages 1026-1036

Publisher

BENTHAM SCIENCE PUBL LTD
DOI: 10.2174/1570193X17999201127105752

Keywords

Covalent organic frameworks; hydrogen storage; water harvesting; methane storage; crystalline polymers; pore surface engineering

Funding

  1. DST, New Delhi [DST/TM/WTI/WIC/2K17/124]

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COFs are covalently bonded polymers synthesized using a bottom-up approach to control the position of building units, resulting in highly regular, rigid, and porous structures for tuning the chemical and physical properties of the network. Applications of COFs in gas storage and water harvesting are comprehensively reviewed in this mini-review.
Covalent Organic Frameworks (COFs) are covalently bonded polymers that are synthesised applying a bottom-up approach using molecular building units that have pre-designed geometry. COFs are crystalline and have control over the position of building units in two and three dimensions, due to which highly regular, rigid, and porous structures can be developed for tuning chemical and physical properties of the network. The present mini-review provides comprehensive overviews of the applications of the COFs in gas storage and water harvesting.

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