4.6 Article

Doubly degenerate diffuse interface models of surface diffusion

Journal

MATHEMATICAL METHODS IN THE APPLIED SCIENCES
Volume 44, Issue 7, Pages 5385-5405

Publisher

WILEY
DOI: 10.1002/mma.7116

Keywords

degenerate Cahn– Hilliard equation; surface diffusion

Funding

  1. EU [766955, 828890]
  2. John von Neumann Institute for Computing (NIC) [HDR06]
  3. JURECA at Julich Supercomputing Centre (JSC) [HDR06]
  4. US National Science Foundation [NSF-DMS 1719854, NSF-DMS 2012634]
  5. TUD
  6. Projekt DEAL

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In this study, we discuss two doubly degenerate Cahn-Hilliard models for isotropic surface diffusion, focusing on degeneracy in the mobility function and a restriction function associated with the chemical potential. Our computational results indicate that the restriction functions provide more accurate approximations of surface diffusion. We also explore a slight generalization of a non-variational model and introduce a new variational and energy dissipative model, both of which can be related to the generalized non-variational model and show convergence to the sharp-interface limit of surface diffusion through formal matched asymptotics.
We discuss two doubly degenerate Cahn-Hilliard (DDCH) models for isotropic surface diffusion. Degeneracy is introduced in both the mobility function and a restriction function associated to the chemical potential. Our computational results suggest that the restriction functions yield more accurate approximations of surface diffusion. We consider a slight generalization of a model that has appeared before, which is non-variational, meaning there is no clear energy that is dissipated along the solution trajectories. We also introduce a new variational and, more precisely, energy dissipative model, which can be related to the generalized non-variational model. For both models, we use formal matched asymptotics to show the convergence to the sharp-interface limit of surface diffusion.

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