Broadening cognizance on atomically thin photocatalysts

Photocatalysts with atomic dimensions exhibit superior performance in photocatalytic applications owing to their large surface-to-volume ratio, enormous surface active sites, and superior light harvesting ability. The single-unit-cell thickness reduces interlayer charge transfer resistance, facilitating the rapid transfer of electrons and holes from the interior to the surface. This review aims to provide a comprehensive discussion on the fundamentals of photocatalysis and the advancements achieved from the evolution of photocatalysts from their bulk-counterpart to atomic dimensions. State-of-the-art techniques in designing and modifying atomically thin photocatalysts, such as defect engineering, impurity doping, facet engineering, and atomic-scale heterojunction construction, for diverse photocatalytic applications will be comprehensively elucidated.

Automated summary

Photocatalysts with atomic dimensions demonstrate superior performance in photocatalytic applications due to their large surface-to-volume ratio, enormous surface active sites, and superior light harvesting ability. The single-unit-cell thickness reduces interlayer charge transfer resistance, facilitating rapid transfer of electrons and holes from the interior to the surface.