Journal
MATERIALS LETTERS
Volume 283, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.matlet.2020.128747
Keywords
Li ion conductor; Low-temperature processing; Particles nanosize; Sol-gel preparation; Ceramics
Funding
- Maekawa Houonkia Foundation
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Cubic garnet-type Li ion conductor c-LLZTO was prepared through the metal alkoxide route with chemical modification, resulting in a dense c-LLZTO pellet with higher ion conductivity at 300 K.
Cubic garnet-type Li ion conductor such as Li7La3Zr1.75Ta0.25O12 (c-LLZTO) are promising materials to develop all-solid-ceramic type Li ion batteries. For this study, we prepared c-LLZTO through the metal alkoxide route with chemical modification. Results show that chemical modification using acetic acid and distilled water for the partial hydrolysis lowered the crystallization temperature of the c-LLZTO with mono-phase at 973 K under ambient atmosphere. The obtained c-LLZTO with 63 nm crystallite size was sintered at 1373 K for 3 h to obtain a dense c-LLZTO pellet. The Li ion conductivity of the sintered c-LLZTO pellet exhibited higher ion conductivity of 3.48 x 10(-4) Scm(-1) at 300 K than those of the reported chemical-solution-derived cubic garnet-type Li ion conductors. (c) 2020 Elsevier B.V. All rights reserved.
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