Structurally Anisotropic Janus Particles with Tunable Amphiphilicity via Polymerization of Dynamic Complex Emulsions

A facile one-step approach for the synthesis of physically and chemically anisotropic polymer particles with tunable size, shape, composition, wettability, and functionality is reported. Specifically, dynamically reconfigurable oil-in-water Janus emulsions containing photocurable hydrocarbon or fluorocarbon acrylate monomers as one of the droplet phases are used as structural templates to polymerize them into precision Janus particles with highly uniform anomalous morphologies including (hemi-) spheres, lenses, and bowls. During polymerization, each interface is exposed to a different chemical environment, yielding particles with an intrinsic Janus character that can be amplified via side-selective postfunctionalization. The fabrication method allows to start with various common emulsification techniques, thus generating particles in the range of 200 nm -150 mu m, also at a technical scale. The anisotropic shape combined with the asymmetric wettability profile of the produced particles promotes their directed self-assembly into colloidal clusters as well as their directional alignment at fluid interfaces. We foresee the application of such Janus particles in technical emulsions or oil recovery, for the manufacturing of programmed self-assembled architectures, and for the engineering of microstructured interfaces.

Automated summary

A facile one-step approach is reported for the synthesis of polymer particles with tunable characteristics, using dynamically reconfigurable oil-in-water Janus emulsions as structural templates. The resulting particles have intrinsic Janus character and can be further functionalized, promoting directed self-assembly and alignment at fluid interfaces. Applications include technical emulsions, oil recovery, manufacturing of self-assembled architectures, and microstructured interfaces engineering.